Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide.
نویسندگان
چکیده
This report presents the synthesis of a tetraphenyladamantane-based microporous polycyanurate network with a BET surface area of 843 m(2) g(-1) and a pore size of 7.8 Å. It uptakes 98.0 wt% benzene (298 K, P/P0 = 0.9), 1.49 wt% H2 (77 K/1 bar) and 12.8 wt% CO2 (273 K/1 bar) with CO2/N2 selectivity of up to 112.
منابع مشابه
Tetraphenyladamantane-based microporous polyimide for adsorption of carbon dioxide, hydrogen, organic and water vapors.
Tetraphenyladamantane-based microporous polyimide was synthesized. It can uptake 14.6 wt% CO2 at 273 K and 1 bar, 99.2 wt% benzene and 59.7 wt% cyclohexane at 298 K and 0.9 bar, exhibiting potential applications in gas storage and recovery of organic pollutants.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 76 شماره
صفحات -
تاریخ انتشار 2014